You can recommend that your friend pulls the 3 4 tiles out and replace them.
Marble tile turning orange.
The first cause is mold which develops from the combination of moisture and warmth in the bathroom.
Well they can either be mold or iron in the water that is discoloring your grout.
Marcescens is commonly found growing in bathrooms especially on tile grout shower corners toilet water line and basin where it manifests as a pink pink orange or orange discoloration and slimy film feeding off phosphorus containing materials or fatty substances such as soap and shampoo residue.
My initial guess is that the orange stain is water damage geting under the tile maybe from the fact there seems to be no silicone joint or the fact there may be pipes in that area possibly with aleak.
If iron is present in the marble tile it will begin to oxidize when exposed to water or other oxidizers such as acids and household bleach.
Not much you can do about it.
If iron is present in the marble tile it will begin to oxidize when exposed to water or other oxidizers such as acids and household bleach.
Answer orange or rust like staining in stone can be caused by minerals within the stone or sometimes because the stone is in close proximity of metal.
Try to clean it pull it out with a poultice will make it worse.
If the marble becomes wet long enough to allow moisture to leach through the marble the iron deposits will oxidize creating yellow orange brown stains.
Kbaby what is that to the left of the orange mark in the picture.
Due to its abundant presence in the environment and its preference for damp conditions s.
It is rust stains that naturally occurs when the iron deposits reacts with water or repeated long term exposure to moisture.
Iron can stain the bathtub and other light colored fixtures that the water touches.
The second cause is excess iron in the water.
Usually it this process occurs over a longer period but if enough moisture it could happen quickly and these tiles are thin.
Depending on what it is there are a few different approaches but i found my simple approach is the easiest and yielded good results.
First of all what are those orange stains in your grout anyways.
In my case i believe it to be iron in the water since we have tried cleaning this tile to no avail for quite some time.
How to clean orange stains in shower.
It is for this reason that we recommend not using white marble in a shower.